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Download Solvomercuration/Demercuration Reactions in Organic Synthesis fb2, epub

by Richard C. Larock

Download Solvomercuration/Demercuration Reactions in Organic Synthesis fb2, epub

ISBN: 0387150943
Author: Richard C. Larock
Language: English
Publisher: Springer Verlag; 1 edition (October 1, 1986)
Pages: 607
Category: Chemistry
Subcategory: Science
Rating: 4.5
Votes: 795
Size Fb2: 1939 kb
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Solvomercuration, Demercuration Reactions in Organic Synthesis. Larock, Professor Richard C.

Solvomercuration, Demercuration Reactions in Organic Synthesis. price for USA in USD (gross). ISBN 978-3-642-88204-3.

Alkene Organische g chemistry development mercury metals organic chemistry organic synthesis reactions synthesis.

Pages 1-2. Hydroxymercuration. Alkene Organische g chemistry development mercury metals organic chemistry organic synthesis reactions synthesis. Authors and affiliations.

erc Reactions Organ Synthesis book. Goodreads helps you keep track of books you want to read. Start by marking erc Reactions Organ Synthesis: as Want to Read: Want to Read savin. ant to Read.

The oxymercuration reaction is an electrophilic addition organic reaction that transforms an alkene into a neutral alcohol. In oxymercuration, the alkene reacts with mercuric acetate (AcO–Hg–OAc) in aqueous solution to yield the addition of an acetoxymercury (HgOAc) group and a hydroxy (OH) group across the double bond. Carbocations are not formed in this process and thus rearrangements are not observed. The first highly stereoselective and quite efficient synthesis of digitoxin (C7) was achieved by a combination of these methods

Solvomercuration, Demercuration Reactions in Organic Synthesis. Diastereoselective deoxymercuration in cyclic system. The first highly stereoselective and quite efficient synthesis of digitoxin (C7) was achieved by a combination of these methods. The furyl-substituted precursor IV of digitoxigenin (Scheme 1) was used as aglycone, and the furan group was converted to the unsaturated lactone of digitoxin by our known oxidation procedure (m-chloroperbenzoic acid/NaBH4) after the assembly of the carbohydrate portion of the molecule and its deblocking was completed.

ercuration Reactions in Organic Synthesis Richard C. Larock. The earlier Springer monograph entitled "Organic Synthesis by Means of Trans i tion Metal Complexes" covered many of the more recent advances in this area. The present volume covers applica tions of the very valuable solvomercuration- demercuration sequence in organic synthesis. Organomercurials have played an important role in organic chemistry for over a century.

I thought that the book was clear and interesting. It explained the reactions in sufficient detail for the first graduate level organic class I took

I thought that the book was clear and interesting. It explained the reactions in sufficient detail for the first graduate level organic class I took. My only complaint was that there was no answer guide. The answers are given as literature references, necessitating that you go look them up.

Organomercury Compounds in Organic Synthesis by Richard Larock (English) Paperba. Solvomercuration, Demercuration Reactions in Organic Synthesis by . ultimate gold & silver precious metals 130 books collection on DVD assaying.

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Key Words: Functional groups/book. R. C. Larock, ercuration Reactions. Larock, Organomercury Compounds in Organic Synthesis.

Key Words: Functional groups/book. Organomercury Compounds in Organic Synthesis. Springer Verlag, Berlin, 1985. Key Words: URY/C C/ALKENES/C-X/Hg/1,/C-X/OH. Key Words: URY/C g/ADDITION/1,2/REDUCTION/C-X/OH. Larock, Comprehensive Organic Transformations. VCH, New York, 1989.

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