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by Arieh Ben-Naim

Download Molecular Theory of Solutions fb2, epub

ISBN: 0199299692
Author: Arieh Ben-Naim
Language: English
Publisher: Oxford University Press; 1 edition (October 5, 2006)
Pages: 400
Category: Chemistry
Subcategory: Science
Rating: 4.7
Votes: 837
Size Fb2: 1435 kb
Size ePub: 1431 kb
Size Djvu: 1429 kb
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This book presents new and updated developments in the molecular theory of mixtures and solutions.

This book presents new and updated developments in the molecular theory of mixtures and solutions. It is based on the theory of Kirkwood and Buff which was published more than fifty years ago. This theory has been dormant for almost two decades. It has recently become a very powerful and general tool to analyze, study and understand any type of mixtures from the molecular, or the microscopic point of view. The traditional approach to mixture has been, for many years, based on the study of excess thermodynamic quantities. This provides a kind of global information on the system.

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Получить до Чт, 30 янв - Пн, 2 мар от Illinois, США., Состояние: Совершенно новый. The aim of this book is to explain the unusual properties of both pure liquid water and simple aqueous solutions, in terms of the properties of single molecules and interactions among small numbers of water molecules.

This book presents new and updated developments in the molecular theory of mixtures and solutions

This book presents new and updated developments in the molecular theory of mixtures and solutions.

The purpose of this book is to present the molecular theory of aqueous fluids based on the framework of the general theory of liquids.

Автор: Ben-naim, Arieh Название: Molecular theory of solutions Издательство: Oxford Academ Классификация . This book presents developments in the molecular theory of mixtures and solutions. Название: Molecular Electronics.

This book presents developments in the molecular theory of mixtures and solutions. Название: Molecular Electronics

Introduction to a Molecular Theory. Introduction to a Molecular Theory.

Molecular Theory of Water, and Aqueous Solutions. This book discusses entropy and the Second Law of Thermodynamic In such way that everyone can understand its subject matter

Molecular Theory of Water, and Aqueous Solutions. Part II: The Role of Water in Protein Folding Self Assembly and Molecular Recognition. World Scientific, Singapore (2010) (For more information). A. Ben-Naim Myths and Verities in Protein Folding Theories, (For more information) World Scientific, Singapore (2016). Ben-Naim TheBriefest History of Times, (For more information) World Scientific, Singapore (2016). This book discusses entropy and the Second Law of Thermodynamic In such way that everyone can understand its subject matter. Entropy is one of the must interesting concepts in physics.

By: Ben-Naim, Arieh, 1934 .

By: Ben-Naim, Arieh, 1934-. Material type: BookPublisher: Oxford ; New York : Oxford University Press, c2006Description: xvi, 380 p. : ill. ; 25 c. SBN: 9780199299690 (acidfree paper); 0199299692 (acidfree paper); 9780199299706 (pbk. : acidfree paper); 0199299706 (pbk. : acidfree paper). Subject(s): Solution (Chemistry) Molecular theoryDDC classification: 54. 4 Online resources: Table of contents Publisher description Contributor biographical information. Tags from this library: No tags from this library for this title.

Books written by Arieh Ben-Naim: Water and Aqueous Solutions: Introduction to a Molecular Theory. Ben-Naim is a modern antagonist of the term entropy. He advocates abandoning the word entropy altogether, and replacing it with "missing information". He also indicates that the Kelvin temperature scale artificially introduces the units of thermodynamic entropy.

This book presents new and updated developments in the molecular theory of mixtures and solutions. It is based on the theory of Kirkwood and Buff which was published more than fifty years ago. This theory has been dormant for almost two decades. It has recently become a very powerful and general tool to analyze, study and understand any type of mixtures from the molecular, or the microscopic point of view. The traditional approach to mixture has been, for many years, based on the study of excess thermodynamic quantities. This provides a kind of global information on the system. The new approach provides information on the local properties of the same system. Thus, the new approach supplements and enriches our information on mixtures and solutions.

Comments:

invasion
Excellent volume but only for the seasoned statistical mechanic. A good introduction to Kirkwood/Buff theory which is the main strength of this work. Novices in solution thermodynamics would be advised to steer clear.
wanderpool
Exactly as described; quick delivery!
Detenta
Crystal clear exposition of the molecular theory of mixtures and solutions based on the inversion of the Kirkwood-Buff theory, which allows to connect measurable quantities to local properties of the system. Among the strength points I would mention clarifying many delicate aspects of deviations from ideal solutions (often sources of confusion), and the introduction of solvation thermodynamics.
Ytli
This is an excellent book that highly succeeds in explaining a difficult subject! Thermodynamics of solution mixtures has a long history and much has been written on this topic. I am amongst those of you that have been confused from time to time by the various definitions of excess functions, activity coefficients and reference states. In "Molecular Theory of Solutions", Ben-Naim introduces the reader to the elementary statistical mechanics of liquids and solution mixtures. A central theme of the book is the Kirkwood-Buff (KB) theory of solution, which, as originally shown by Ben-Naim, can be used to extract (local) molecular properties from (global) thermodynamic properties. Ben-Naim next uses KB theory to derive a thermodynamic formalism for ideal- and nonideal solutions. I was intrigued when first reading this newly derived formalism. Being educated to calculate "deviations from Raoult" (just numbers, nothing more), suddenly nonideality acquired a very clear microscopic significance. Beautiful! I highly recommend this book to anybody interested in the subject, in particular to those of you that teach it.
Mr_Mole
This book is very important and necessary for the chemistry and biochemistry. The special interest presents a new definition of solvation. In the traditional definition one needs to specify the standard state for the solute in the ideal gas and liquid phase. It is the reason of some confusion concerning the "standard state" that exists in the literature. The confusion arises from the fact that the solvation Gibbs energy Äìs* is determined experimentally in a similar way as one of the conventional standard Gibbs energy of solvation. The latter does involve a choice of standard state. Moreover in all the conventional processes the standard quantities apply only to very dilute solutions of solute in the system, i.e. it could be studied only in the concentration range when Henry's law is obeyed. This is a very severe restriction on the applicability of the standard quantities. In Ben-Naim's definition of a new process of solvation there is no need to specify any standard state for the solvation. This is quite clear from the definition of the solvation process. In addition the process of Ben-Naim's solvation and the corresponding thermodynamic quantities can be defined for the concentrated solutions and pure liquids.
Steelrunner
This is an important book that provides a clear account of the molecular theory of solutions and mixtures based mainly on the Kirkwood-Buff theory that was developed many years ago. The theory could not have been fully exploited until Ben-Naim developed methods to calculate the Kirkwood-Buff (KB) integrals from experimental data rather than from the pair correlation functions.

The KB integrals, as well as some derived quantities, provide information about the local properties of the system, as opposed to their global properties described by the excess thermodynamic functions that were and are commonly used. Ben-Naim also introduced a new measure of the thermodynamics of solvation that does not depend on hypothetical standard states that were traditionally part of solution chemistry. The book is written very clearly and the arguments are carefully presented and illustrated with examples. It is strongly recommended for both the beginning graduate student and experienced scientist with interests in solutions.

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